인산염 황산염

Phosphate sulfate

인산염 황산염은 인산염과 황산염 이온을 모두 포함하는 혼합 음이온 화합물이다.관련 화합물로는 황산비소화합물, 인산셀렌산염 및 비산셀렌산염이 있다.

일부 인산수소 황산염은 초단백질 도체이다.

목록.

화학 물질 음 결정계 스페이스 그룹 단위 셀 용량 밀도 댓글 레퍼런스
산후아나이트 Al2(PO4)(SO4)(OH)·9호2 [1]
핫소나이트 Al11(SO4)3(PO4)2(OH)21 · 16H2O 삼사정형의 a=11.23, b=11.66 c=10.55 α=112°32도, β=12°32도 =64°27도 굴절 : α = 1.519 µ = 1.521 [2]
아랑가사이트 Al2F(PO4)(SO4)·9호2 단사정형의 P2/a a = 7.073, b = 9.634, c = 10.827, β = 100.40°, Z = 2 725.7 [3]
페이즐라이트 Na3Al16(SO4)2(PO4)10(OH)17 · 20H2O 단사정형의 a 13.31, b 12.62, c 23.15, β 110.0°, Z = 2 신용이 떨어졌다 [4]
페이즐라이트 Na2Al9[(P,S)O4]8(OH)6·28H2O 삼사정형의 P1 a = 9.28, b = 11.98, c = 13.25, α = 91.3, β = 75.6, β = 67.67°, Z = 4 1308 [5]
우드하우스석 CaAl3(PO4)(SO4)(OH)6 삼각형의 R3m a = 6.993, c = 16.386 693.95 3.0 단축(+nω) = 1.636nε = 1.647 복굴절: θ = 0.011 [6]
아르데알라이트 CaH2(PO4)(SO4)• 4호2 단사정형의 a = 5.721, b = 30.95, c = 6.265, β = 117.26° Z = 4 986.11 2.32 [7]
데스티네자이트 디아도카이트 Fe2(PO4)(SO4)(OH)•6호2 삼사정형의 P1 a = 9.570, b = 9.716, c = 7.313, α = 98.74°, β = 107.90°, β = 63.86°Z = 2 [8]
보후슬라바이트 FeIII4(PO4)(3SO4)(OH)(HO2)·10nHO2(55 n 14 14) 삼사정형의 P1 a = 13.376 b = 13.338 c = 10.863 α = 92.80, β = 91.03, θ = 119.92°, Z = 2 1675.7 핑크색 [9]
보리카이트 (Ca,Mg)(Fe3+,Al)(4PO4,SO4,CO3)(OH)/83-7.5호2 [10]
카마로네사이트 [Fe3+(HO2)(2POOH3)](2SO4) · 1 ~ 2호2 삼각형의 R32 a = 9.0833, c = 42.944, Z = 9 3068.5 [11]
Fe3+4(PO4)3(SO4)(OH)·18호2 삼사정형의 P1 a=13.376, b 13.338, c 10.863, α 92.80, β 91.03, β 119.92° 1675.7 [12]
밴더헤이덴석 Zn6(PO4)2(SO4)(OH)4·7호2 단사정형의 P21/n a = 6.16 b = 19.619, c = 7.782, β = 90.67° 947.1 이축(–)α = 1.565, β = 1.580 µ = 1.582. 2V = 39.8° [13]
스반베르가이트 SrAl3(PO4)(SO4)(OH)6 삼각형의 R3m a = 6.97, c = 16.59 Z = 3 697.98 3.2 단축 (+) nω = 1.631 - 1.635ε n = 1.646 - 1.649 복굴절: θ = 0.015 [14]
버차이트 CdCu22(PO4)(2SO4) · 5HO2 a = 10.489 b = 20.901 c = 6.120 Z = 4 1349.6 3.647 2축 양성,

nα = 1.624, nβ = 1.636, nγ = 1.669, 2Vcalc = +63°

[15]
코크라이트 PbFe3(OH)6 SOPO 삼각형의 R3m a = 7.32, c = 17.02 Z = 3 781.2 4.295 단축(-) nω = 1.930ε n = 1.930 n = 1.93 - 1.96 복굴절 0.03 [16]
BaAl3(PO4)(SO4)(OH)6 삼각형의 R3m a = , c = Z = 3 [17]
힌스달라이트 (Pb,Sr)Al3(PO4)(SO4)(OH)6 [18]
쓰메바이트 PbCu2(PO4, SO4)(OH) [19]
델보사이트 CaFe43+(PO4, SO4)(2OH)·84~6호2 [20]
로시안토나이트 Al3(PO4)(SO4)2(OH)2(H2O)10·4호2 삼사정형의 P1 a = 10.3410, b = 10.9600, c = 11.1446, α = 86.985, β = 65.727, β = 75.064°, Z = 2 1110.5 [21]
슐로스마허라이트 (H3O,Ca)Al3(AsO4,PO4,SO4)2(OH)6 [22]
아더라이트 Cu(Fe3+)2(AsO4,PO4,SO4)2(O,OH)2·4(H2O) [23]
코발타르토라이트 [23]
포스포넬라이트 Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3 삼사정형의 P1? a = 5.38, b = 7.10, c = 14.76, α = 99.00°, β = 94.94°, β = 90.14°Z = 1 555 3.82 2축(+), α = 1.730, β = 1.745, β = 1.764, 2V 90° [24]
프랑코라이트 (Ca, Mg, Sr, Na)10(PO4, SO4, CO3)6F2–3 [25]
Al4(UO2)2(PO4)4(SO4)(OH)2 · 18H2O [26]
Al4(UO2)2(PO4)4(SO4)(OH)2 · 20H2O [26]
코코니나이트 Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O 단사정형의 C2/c a = 12.45, b = 12.96, c = 17.22, β = 105.7° [26]
샹장석 Fe2Al2(UO2)2(PO4)4(SO4)(OH)2 · 22H2O 사각형 a = 7.17Ω, b = 7.17Ω, c = 22.22Ω Z=1 1,142 이축(-)nα = 1.558nβ = 1.576nγ = 1.593 2V: 87° [27]

인조

화학 물질 음 결정계 스페이스 그룹 단위 셀 † 용량 밀도 댓글 레퍼런스
[HN4+]2 · HSO4− · HPO24− [28][29]
NH4(HSO4)0.45(H2PO4)0.55 직교 혈전성 [30]
18 크라운[6]·[NH4][HPO244] [0.5HSO]0.5 ·호2 오르트롬의 F2dd a=8.710 b=28.868 c=31.199 Z=16 7846 1.346 70도에서 탈수하다 [31]
[(CH25)4N+]2HSO4−·H2PO4− 단사정계 C2/c a = 28.0787 b = 11.8671 c = 14.1533 β = 100.739° Z = 8 4633.46 1.303 무색, 353K에서 분해 [32]
(NH2CH2COOH)3(H2SO4)0.7(H3PO4)0.3 단사정형의 TGSP라고 하는, 무색, 강유전체, 퀴리점 51°C, 초유전체
Na(HSO4)(H3PO4) 단사정형의 P 21 a = 5.449, b = 6.832, c = 8.718, β = 95.88°, Z = 2 322.8 [33]
K2(HSO4)(H2PO4) 단사정형의 P21/c a = 11.150, b = 7.371, c = 9.436, β = 92.29°, Z = 4 774.9 [33]
K4(HSO4)3(H2PO4) 삼사정형의 P 1 a = 7.217, b = 7.521, c = 7.574, α = 71.52°, β = 88.28°, β = 86.20°, Z = 1 389.1 [33]
K4(PO2F2)2(S2O7) 534.46 단사정형의 C2/c a = 13.00, b = 7.543, c = 19.01, β = 130.07°, Z = 4 1426.5 2.489 무색; 피로황산염 + 디플루오로인산염 [34]
K3[OSOPOSO323] [35]
HTi1−x2(PO4)(3−xSO4)(xx=0.5–1) [36]
Na2MgTi(SO4)(PO4)2 삼각형의 R3c a=8.4796 c=21.8091 Z=6 1358.1 2.818 [37]
K2MgTi(SO4)(PO4)2 입방체의 P213 a=9.8743 Z=4 962.84 2.872 [37]
Ca10-xNax(PO4)6-x(SO4)xF2 단사정형의 [38]
NaFe2(PO4)(SO4)2 육각형의 R3c a=8.4243 c=21.973 [39]
NaFe1.4V0.6(PO4)(SO4)2 [40]
[Ni(CHN14104)](34PO4)(2SO4)(CHN14104=2,2'-bi-1H-벤즈이미다졸) 3331.96 입방체의 I43d a = 24.964 Z = 4 15558 1.423 초록의 [41]
Rb2(HSO4)(H2PO4) 단사정형의 P21/n a=7.448, b=7.552, c=7.632, β=100.47°, Z=2 422.1 [42][43]
Rb2(HSO4)(H2PO4) 단사정형의 P21/c a=11.555, b=7.536, c=9.593, β=91.56, Z=4 853.0 16,000으로 [43]
Rb4(HSO4)3(H2PO4) 직교 혈전성 P21212 a=7.612, b=14.795, c=7.446, Z=2 838.6 [42][43]
18 크라운[6]/Rb[HPO24]0.5 [HSO4]0.5 · 3호2 단사정형의 C2/c a=19.199 b=8.447 c=25.199 β=101.00° Z=8 4232 1.572 70도에서 탈수하다 [31]
Rb2MgTi(SO4)(PO4)2 [37]
Sr4(PO4)2 SO4 [44]
NaZrMg(PO4)(SO4)2 육각형의 R3c [45]
NaZrCo(PO4)(SO4)2 육각형의 R3c [45]
NaZrNi(PO4)(SO4)2 육각형의 R3c [45]
NaZrCu(PO4)(SO4)2 육각형의 R3c [45]
NaZrZn(PO4)(SO4)2 육각형의 R3c [45]
NaZrAl(PO4)2(SO4) 육각형의 R3c [45]
NaZrFe(PO4)2(SO4) 육각형의 R3c [45]
H3OSb2(SO4)2(PO4) 삼사정형의 P1 a=5.134 b=7.908 c=12.855, α=81.401°β=87.253° =86.49° [46]
KSb2(SO4)2(PO4) 삼사정형의 P1 a=5.1453 =7.9149 c =12.6146,α=82.054°β=87.715°θ=86.655° [46]
RbSb2(SO4)2(PO4) 삼사정형의 P1 a=5.1531 b=7.957 c=12.845, α=81.801°β=87.676° =86.703° [46]
Cs2(HSO4)(H2PO4) 입방체의 ao=4.926 105°C 이상, 과냉각 가능 [47]
Cs2(HSO4)(H2PO4) 단사정형의 P21/n a = 7.856 b = 7.732 c = 7.827, β = 99.92° Z = 2 468.3 3.261 2.3% 암모늄을 대체할 수 있습니다. 110°C에서 양성자 전도율은 3×10µcm입니다−3−1−1. [48][49]
Cs3(HSO4)2(H2PO4) 단사정형의 C2/c a=19.824 b=7.859 c=19.047 β=100.20° Z=4 1387.2 3.302 수용액 298-313K에 대해 안정적, 411K에서 상전이 [50]
Cs4(HSO4)3(H2PO4) 단사정형의 C2/c a=19.945 b=7.8565 c=8.9949 β=100.119° Z=3 1387.5 3.301 무채색의 [51][52]
Cs5(HSO4)2(H2PO4)3 입방체의 I43d a=14.5668 381K 이상이 정사각형 a=4.965 c=5.016으로 이동합니다. [53]
Cs6H(HSO4)3(H2PO4)4 입방체의 I43d a=14.4758 3033.38 3.236 무채색의 [54]
Cs5(HSO4)3(H2PO4)2 단사정형의 C2/c a=34.07Ω,b=7.661,c=9.158,β=90.44° 2390 3.198 [55]
18 크라운 [6]·Cs[HPO24]0.5 [HSO4]0.5 · 3호2 단사정형의 C2/c a=19.840 b=8.460 c=26.19 β=101.14 Z=8 4313 1.689 70도에서 탈수하다 [31]
CsNH4(HSO4)(H2PO4) [56]
Cs3NH4(HSO4)3(H2PO4) [56]
Cs2MgTi(SO4)(PO4)2 [37]
Ba4(PO4)2SO4 [44]
NaBa6Zr(PO4)5그러니까4 입방체의 I43d a = 10.5449 Z = 4 1172.54 율리타이트 광물 구조 [44]
Ba2Sr2(PO4)2그러니까4 [44]
Ba3Sr(PO4)2그러니까4 [44]
Ce2O(HPO4)2(SO4). 4H2O CeIV [57]
Ce2O(HPO4)2.4(SO4)0.6. 2H2O CeIII [58]
[enH2]0.5 [CeIII(PO4)(HSO4)(OH2)] 단사정형의 P21/a a=12.999 b=7.150 c=9.212 β=95.33 크림색 [59]
KSr2Eu(PO4)2그러니까4 [44]
RbSr2Eu(PO4)2그러니까4 [44]
CsSr2Eu(PO4)2그러니까4 [44]
[enH2]0.5 [호(HPO4)(SO4)(HO2)] 단사정형의 P21/a a = 12.938 b = 6.834 c = 9.100 β = 88.12° [60]
Pb2Mg2(PO4)2그러니까4 [44]
MgPb3(PO4)2(SO4) 입방체의 I43d a = 10.199 Z = 4 1092.4 5.67 [61]
CaPb3(PO4)2(SO4) 입방체의 I43d a = 10.296 Z = 4 1091.5 5.77 [61]
MnPb3(PO4)2(SO4) 입방체의 I43d a = 10.258 Z = 4 1079.4 5.92 [61]
CoPb3(PO4)2(SO4) 입방체의 I43d a = 10.356 Z = 4 1110.6 5.78 [61]
NiPb3(PO4)2(SO4) 입방체의 I43d a = 10.434 Z = 4 1135.9 5.65 [61]
CuPb3(PO4)2(SO4) 입방체의 I43d a = 10.422 Z = 4 1132.0 5.70 [61]
ZnPb3(PO4)2(SO4) 입방체의 I43d a = 10.449 Z = 4 1140.8 5.67 [61]
CdPb3(PO4)2(SO4) 입방체의 I43d a = 10.315 Z = 4 1097.5 6.17 [61]
SrPb3(PO4)2(SO4) 입방체의 I43d a = 10.369 Z = 4 1114.8 5.93 [61]
Th2(PO44)2 SO·22 HO 450°C 분해 [62]

유기 유도체

황과 인이 산소 원자에 결합되어 있는 염화술포인산염.생화학에서 황산염의 대사에는 예를 들어 아데노신-5'-[63]포스포황산염과 같은 군을 사용할 수 있다.

레퍼런스

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